Smectic ordering in liquid-crystal-aerosil dispersions. II. Scaling analysis.

نویسندگان

  • Germano S Iannacchione
  • Sungil Park
  • Carl W Garland
  • Robert J Birgeneau
  • Robert L Leheny
چکیده

Liquid crystals offer many unique opportunities to study various phase transitions with continuous symmetry in the presence of quenched random disorder (QRD). The QRD arises from the presence of porous solids in the form of a random gel network. Experimental and theoretical work supports the view that for fixed (static) inclusions, quasi-long-range smectic order is destroyed for arbitrarily small volume fractions of the solid. However, the presence of porous solids indicates that finite-size effects could play some role in limiting long-range order. In an earlier work, the nematic-smectic-A transition region of octylcyanobiphenyl (8CB) and silica aerosils was investigated calorimetrically. A detailed x-ray study of this system is presented in the preceding paper, which indicates that pseudocritical scaling behavior is observed. In the present paper, the role of finite-size scaling and two-scale universality aspects of the 8CB+aerosil system are presented and the dependence of the QRD strength on the aerosil density is discussed.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Smectic ordering in liquid-crystal-aerosil dispersions. I. X-ray scattering.

Comprehensive x-ray scattering studies have characterized the smectic ordering of octylcyanobiphenyl (8CB) confined in the hydrogen-bonded silica gels formed by aerosil dispersions. For all densities of aerosil and all measurement temperatures, the correlations remain short range, demonstrating that the disorder imposed by the gels destroys the nematic (N) to smectic-A (SmA) transition. The sme...

متن کامل

Calorimetric study of the nematic to smectic-A and smectic-A to smectic-C phase transitions in liquid-crystal-aerosil dispersions.

A high-resolution calorimetric study has been carried out on nanocolloidal dispersions of aerosils in the liquid crystal 4-n-pentylphenylthiol-4'-n-octyloxybenzoate (8S5) as a function of aerosil concentration and temperature spanning the smectic-C to nematic phases. Over this temperature range, this liquid crystal possesses two continuous XY phase transitions: a fluctuation-dominated nematic t...

متن کامل

Effect of a quenched random field on a continuous symmetry breaking transition: nematic to smectic-A transition in octyloxycyanobiphenyl-aerosil dispersions.

High-resolution x-ray diffraction and ac-calorimetric experiments have been carried out on the liquid-crystal octyloxycyanobiphenyl in which aerosil particles are dispersed. The measurements were made over a temperature range around the bulk nematic to smectic-A transition temperature. At this transition the liquid crystal breaks translational symmetry in a single direction. The silica particle...

متن کامل

High-resolution x-ray study of nematic-smectic-A and smectic-A-reentrant-nematic transitions in liquid-crystal-aerosil gels.

We have studied the effects of quenched random disorder created by dispersed aerosil nanoparticle gels on the nematic to smectic- A (N- SmA ) and smectic- A to reentrant nematic ( SmA -RN) phase transitions of thermotropic liquid-crystal mixtures of hexyloxycyanobiphenyl (6OCB) and octyloxycyanobiphenyl (8OCB). These effects are probed using high-resolution synchrotron x-ray diffraction techniq...

متن کامل

Smectic-A and smectic-C phases and phase transitions in 8S5 liquid-crystal-aerosil gels.

High-resolution x-ray scattering studies of the nonpolar thermotropic liquid crystal 4-n-pentylphenylthiol-4'-n-octyloxybenzoate (8S5) in aerosil gel nanonetworks reveal that the aerosil-induced disorder significantly alters both the nematic to smectic-A and smectic-A to smectic-C phase transitions. The limiting 8S5 smectic-A correlation length follows a power-law dependence on the aerosil dens...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Physical review. E, Statistical, nonlinear, and soft matter physics

دوره 67 1 Pt 1  شماره 

صفحات  -

تاریخ انتشار 2003